Choosing a group of colours can be a daunting exercise. OK, so there’s some golden rules to follow, like “always choose from the same third of the colour wheel”. Golden rules are made to be broken.
Adobe has a colourful website to make this a bit easier. If you sign in you can download the colourways as a .ase which can be imported to CS2 and CS3 applications via the Swatches palette (InDesign CS2/CS3: Load Swatches; Illustrator CS2/CS3: Open Swatch Library: Other Library; Photoshop CS2/CS3: Load Swatches). A pleasure to use!